Uhlobo, ukusebenza kanye nokusetshenziswa kwe-electrode
Uhlobo lwe-Electrode
Ama-electrode e-Carbonaceous angahlukaniswa abe ama-electrode ekhabhoni, ama-electrode angamagraphite kanye nama-electrode aziphekela ngokuya ngokusetshenziswa kwawo nezinqubo zokukhiqiza.
I-carbon electrode yenziwe nge-low-ash anthracite, i-coke ye-metallurgical, i-pitch coke ne-petroleum coke. Yakhiwe ngesilinganiso esithile kanye nosayizi wezinhlayiyana. Lapho wengeza, i-asphalt ye-binder netiyela kuyaxutshwa, futhi ingxube inyakaziswa ngokulinganayo ekushiseni okufanele. Ukwakha, futhi ekugcineni kancane calcining ku-roaster. Ingahlukaniswa ngama-electrode emvelo e-graphite, ama-electrode e-graphite okwenziwa, ama-carbon electrode kanye nama-electrode ekhabhoni akhethekile.
I-graphite electrode (graphiteelectrode) yenziwe nge-petroleum coke kanye ne-pitch coke njengento eluhlaza, bese ifakwa esithandweni somlilo esine-graphitized kagesi esinokushisa kwe-2273 ~ 2773K, futhi senziwe i-graphite electrode nge-graphitization. I-electrode yegraphite iphinde ihlukaniswe yaba Uhlobo olulandelayo.
I-electrode yamandla e-graphite evamile ivumela ukusetshenziswa kwama-electrode e-graphite anobuningi bamanje obungaphansi kuka-17 A/cm2, futhi isetshenziselwa ikakhulukazi izithando zamandla ezijwayelekile ezifana nokwenza insimbi, ukucwengwa kwe-silicon, ne-phosphorus ephuzi.
Ingaphezulu le-anti-oxidation coated graphite electrode limbozwe ungqimba oluyisivikelo (i-graphite electrode antioxidant) eqhubayo futhi imelana ne-oxidation yokushisa ephezulu, enciphisa ukusetshenziswa kwama-electrode ngesikhathi sokwenziwa kwensimbi (19%~50%) futhi yandise impilo yesevisi. ye-electrode (22% ~ 60%), ukunciphisa ukusetshenziswa kwamandla kwe-electrode.
I-electrode ye-graphite enamandla amakhulu ivumela ukusetshenziswa kwama-electrode e-graphite anomthamo wamanje we-18 kuya ku-25 A/cm2, osetshenziswa kakhulu kuma-arc anamandla kagesi aphezulu ukwenza insimbi.
Ama-electrode egraphite anamandla aphezulu avumela ukusetshenziswa kwama-electrode egraphite anokuminyana kwamanje okukhulu kuno-25 A/cm2. Isetshenziswa kakhulu kuma-ultra-high power steelmaking arc furnaces kagesi.
I-electrode yokuzibhakela (selfbakingelectrode) isebenzisa i-anthracite, i-coke, nebitumen netiyela njengezinto zokusetshenziswa, yenza ukunamathisela kwe-electrode ezingeni lokushisa elithile, bese ilayisha ukunamathisela kwe-electrode kukesi le-electrode elifakwe esithandweni sikagesi (njengoba kubonisiwe. ku-FIG. esithandweni ziyazenzela futhi ziphekwe. I-electrode enjalo ingasetshenziswa ngokuqhubekayo, futhi ingakhiwa ngokujoyina unqenqema olude oluseceleni futhi ingaxoshwa ibe ububanzi obukhulu. I-electrode yokubhaka isetshenziswa kabanzi ekukhiqizeni i-ferroalloy ngenxa yenqubo yayo elula nezindleko eziphansi.
Umfanekiso 1 Umdwebo ohleliwe wegobolondo le-electrode
Igobolondo le-electrode elingu-1; 2-izimbambo ucezu; Ulimi olunxantathu
Ukusebenza okuyinhloko kwezobuchwepheshe kwe-electrode
Izinto ze-electrode kufanele zibe nezinto ezilandelayo ze-physicochemical:
I-conductivity ingcono, i-resistivity incane, ukunciphisa ukulahlekelwa kwamandla kagesi, ukunciphisa ukwehla kwe-voltage enetha elifushane, nokwandisa i-voltage ephumelelayo ukwandisa amandla echibi elincibilikisiwe;
Iphuzu lokuncibilika liphezulu;
I-coefficient yokwanda okushisayo incane, lapho izinga lokushisa lishintsha ngokushesha, akulula ukukhubazeka, futhi ukucindezeleka kwangaphakathi okubangelwa ukushintsha kwezinga lokushisa akukwazi ukukhiqiza imifantu emihle ukuze kwandiswe ukumelana;
Yiba namandla anele emishini emazingeni okushisa aphezulu;
Ukungcola kuncane futhi ukungcola akungcolisi i-smelt.
Izici eziyinhloko zobuchwepheshe ze-carbon electrode, i-electrode yegraphite kanye ne-electrode yokuziphekela ikhonjisiwe kuThebula 1 kanye neMifanekiso 2 no-3.
Ithebula 1 Ukusebenza kobuchwepheshe kwe-Electrode
Umdwebo 2 Ushintsho lwe-resistivity ye-carbon electrode ne-graphite electrode ngezinga lokushisa
Umfanekiso 3 I-Thermal conductivity ye-carbon ne-graphite electrode njengomsebenzi wezinga lokushisa
Ukukhethwa kwama-electrode embonini ye-ferroalloy
Ama-electrodes azibhaka asetshenziswa kakhulu ekuncibilikiseni i-iron alloy, ekucwengisiseni i-ferrosilicon, i-silicon chromium alloy, i-manganese silicon alloy, i-high carbon ferromanganese, i-high carbon ferrochrome, i-carbon ferromanganese ephakathi nephansi, i-carbon ferrochrome ephakathi nephansi, i-silicon calcium alloy, i-tungsten iron Linda . Ama-electrode okuzibhakela avame ukwandisa ukukhiqizwa kwama-alloys, amabhande ensimbi abe yikhabhoni, futhi akhiqize ama-alloys ensimbi nezinsimbi ezihlanzekile ezinokuqukethwe kwekhabhoni ephansi kakhulu. Uma i-carbon ferrochrome, i-silicon yezimboni nensimbi ye-manganese, i-carbon noma i-graphite electrode kufanele isetshenziswe.
电极的种类、性能及其用途
电极种类
碳质电极按其用途及制作工艺不同可分為碳素电极、石墨电极和自焙电极三种.
碳素电极(carbonelectrode)是以低灰分的无烟煤、冶金焦、沥青焦和石油焦為原料,按一定的比例和粒度组成.混合时加入黏结剂沥.青和焦油,在适当的温度下搅拌均匀后压制成形,最后在焙烧炉缓慢焙烧制得。可分為天然石墨电极、人造石墨电极、碳电极以及特种碳素电极四类。
石墨电极(graphiteelectrode)以石油焦和沥青焦為原料制成碳素电极,再放到温度為2273〜2773K的石墨化电阻炉中,经石墨化而制成石墨电极„石墨电极又分為以下几。
普通功率石墨电极允许使用电流密度低于17A/cm2的石墨电极,主要用于炼钢、炼硅、炼黄磷等的普通功率电炉。
抗氧化涂层石墨电极表面涂覆既能导电又耐高温氧化的保护层(石墨电极抗氧化剂),降低炼钢时的电极消耗(19%〜50%),延长电极的使用寿命(22%〜60%),降低电极的电能消耗。
高功率石墨电极允许使用电流密度為18〜25A/cm2的石墨电极,主要用于炼钢的高功率甉。
超高功率石墨电极允许使用电流密度大于25A/cm2的石墨电极。主要用于超高功率炼钢电。
自焙电极(selfbakingelectrode)用无烟煤、焦炭以及沥青和焦油为原料,在一定温度下制成电极糊,然后把电极糊装入已安装在电炉上的电极壳中(如图1所示),在电炉上的电极壳中(如图1所示)中依靠电流通过时所产生的焦耳热和炉内传导热,自行烧结焦化。边给结成形,且可焙烧成大直径的。自焙电极不仅工艺简单,成本也低,因
图1 电极壳示意图
1-电极壳;2-筋片;3-三角形舌片
电极的主要技术性能
电极材料应具有下列物理化学特性:
导电性要好,电阻率要小,以减少电能的损失,减少短网压降,提高有效电压,以提高熔,以提高熔;
熔点要高;
热膨胀系数要小,当温度急变时,不易变形,不能因温度变化带來的内应力产生绂小的蔚小的内应力产生绂小细小的蔚小;
高温下要有足够的机械强度;
杂质要低,而且杂质不污染所冶炼的品种。
碳素电极、石墨电极和自焙电极的主要技术性能如表1和图2、图3所示.
表1 电极技术性能
图2 碳素电极和石墨电极电阻率随温度的变化情况
图3 碳素电极和石墨电极热导率随温度的变化情况
铁合金工业中电极的选用
自焙电极广泛用于铁合金冶炼,炼制硅铁、硅铬合金、锰硅合金、高碳锰铁、高碳铬铁、中低碳锰铁、中低碳铬铁、硅钙合金、钨铁等。自焙电极易使生产合金增碳,铁皮带入碳,生产含碳很低的铁合金和纯金属,如果碳铬铁、工业硅和金属锰应采用碳素电极或石墨电极。
Isikhathi sokuthumela: Nov-18-2019